Entrapment of liquid is associated with specific materials that absorb
liquid and swell into a “gel.” A simple model of this behavior is based on the
idealization of this gel as a volume of individual spherical particles of equal
radius .
Tanaka
and Fillmore (1979) show that, when a single sphere of such material is
fully exposed to liquid, its radius change can be modeled as
where
is the fully swollen radius approached as
and N,
and
are material parameters. Tanaka and Fillmore also show the first term in the
series dominates, so the model can be simplified to
This provides the rate form
When the gel particles are only partially exposed to liquid (in an
unsaturated system), it seems reasonable to assume that the swelling rate will
be lessened according to the level of saturation. Further, we assume that the
gel will swell only when the saturation of the surrounding medium exceeds the
effective saturation of the gel, ,
where
is the radius of a gel particle that is completely dry. We combine these into a
simple, linear effect:
where
if ,
otherwise.
The packing density and swelling may cause the gel particles to touch. In
that case the surface available to absorb and entrap liquid is reduced until,
if the gel particles occupy the entire volume except for solid material, liquid
entrapment must cease altogether. With
gel particles per unit reference volume, the maximum radius that the gel
particles can achieve before they must touch (in a face center cubic
arrangement) is
and the volume is entirely occupied with gel and solid matter when the
effective gel radius is
The gel swelling behavior is, therefore, further modified to be
Thus, in an unstressed medium the entrapped liquid volume is assumed to be
where
where
is defined by the integration of
Equation 3.
This entrapped liquid can be compressed by pressure so that, when the porous
medium is under stress, we assume
and thus
Combining this with
Equation 1
and neglecting small terms compared to unity then provides
We assume that, in the initial state, the effective saturation of the gel is
the same as the saturation of the surrounding medium:
The constitutive behavior of the gel containing entrapped fluid is given by
the elastic bulk relationship
where
is the average pressure stress in the gel fluid and
is its volumetric effective strain.