**----------------------------------------------- ** CATHODE **----------------------------------------------- **----------------------------------------------- *material, name=ABQ_EChemPET_matCathode *density 2292.0 *conductivity 1.e-4 *specific heat 900. *include, input= ecker-electrolyte_propParam-discharge.inp *Parameter Table, Type="ABQ_EChemPET_Electrode_Definition", Label="ABQ_EChemPET_Electrode_Definition" "Cathode_NMC60", "Cathode", 0.704, 0.296, 0.0, 0.42, 1.0, 0.068, 0.544, 0.544, 0.544, 1.0 *Parameter Table, Type="ABQ_EChemPET_Electrode_Particles", Label = "ABQ_EChemPET_Cathode_NMC60_Particles" "Particle1", 6.49e-06, 1.0, 12630.8, "Formulation_Concentration" ** *Parameter Table, Type="ABQ_EChemPET_Electrode_Particle_Layers", Label="ABQ_EChemPET_Cathode_NMC60_Particle1_Layers" "Layer1", 1.0 *Parameter Table, Type="ABQ_EChemPET_Electrode_Particle_Layer_Diffusion", Label="ABQ_EChemPET_Cathode_NMC60_Particle1_Layer1_Diffusion" 48580.0 , "DiffusionModel_Tabular", "DiffusionModel_ChemoMech" *Parameter Table, Type="ABQ_EChemPET_Electrode_Particle_Layer_Discretization",Label="ABQ_EChemPET_Cathode_NMC60_Particle1_Layer1_Discretization" 100, "Quadratic" ** 100, "Uniform" *** ** *Property Table, Type="ABQ_EChemPET_Electrode_Particle_Layer_DsTabular", Label="ABQ_EChemPET_Cathode_NMC60_Particle1_Layer1_DsTabular" ******* , - Ecker JEs 2015a Fig 9 (b) GITT case ******* [m2/s] [-] (normalization) 6.30957E-14 , 0 1.84566E-13 , 0.136194918 3.29754E-13 , 0.196096722 3.06461E-13 , 0.259226 2.60104E-13 , 0.320812193 1.93242E-13 , 0.381641691 1.36783E-13 , 0.44247938 7.11086E-14 , 0.504927735 2.81544E-14 , 0.567422167 4.49729E-15 , 0.630070191 5.37291E-14 , 0.691988143 1.99639E-13 , 0.752545271 1.54738E-13 , 0.813757212 1.30537E-13 , 0.876513263 1.99868E-14 , 0.939168454 5.30783E-15 , 1.000172023 *Parameter Table, Type="ABQ_EChemPET_Arrhenius", Label = "ABQ_EChemPET_Cathode_NMC60_Particle1_Layer1_DiffArrhenius" 80600., 296.15, ***-------------------------------------------- *Property Table, Type="ABQ_EChemPET_Electrode_Particle_Layer_OCPTabular", Label="ABQ_EChemPET_Cathode_NMC60_Particle1_Layer1_OCPTabular" ***** , , ***** [V] [-] (normalization) [K] - Ecker JES 2015a Fig 5(a) 4.582938389, 0 4.545023697, 0.040268456 4.526066351, 0.087248322 4.469194313, 0.134228188 4.393364929, 0.182885906 4.298578199, 0.228187919 4.213270142, 0.275167785 4.146919431, 0.322147651 4.08056872, 0.365771812 4.033175355, 0.411073826 3.985781991, 0.463087248 3.952606635, 0.505033557 3.928909953, 0.55033557 3.91943128, 0.57885906 3.909952607, 0.620805369 3.900473934, 0.67114094 3.881516588, 0.714765101 3.819905213, 0.765100671 3.748815166, 0.812080537 3.706161137, 0.855704698 3.6492891, 0.901006711 3.578199052, 0.947986577 3.511848341, 1 *Parameter Table, Type="ABQ_EChemPET_Electrode_Particle_Layer_OCPTabularNoInterp", Label="ABQ_EChemPET_Cathode_NMC60_Particle1_Layer1_OCPTabularCharge" ***** , , ***** [V] [-] (normalization) [K] - Ecker JES 2015a Fig 5(a) 4.582938389, 0 4.545023697, 0.040268456 4.526066351, 0.087248322 4.469194313, 0.134228188 4.393364929, 0.182885906 4.298578199, 0.228187919 4.213270142, 0.275167785 4.146919431, 0.322147651 4.08056872, 0.365771812 4.033175355, 0.411073826 3.985781991, 0.463087248 3.952606635, 0.505033557 3.928909953, 0.55033557 3.91943128, 0.57885906 3.909952607, 0.620805369 3.900473934, 0.67114094 3.881516588, 0.714765101 3.819905213, 0.765100671 3.748815166, 0.812080537 3.706161137, 0.855704698 3.6492891, 0.901006711 3.578199052, 0.947986577 3.511848341, 1 *Parameter Table, Type="ABQ_EChemPET_Electrode_Particle_Layer_OCPTabularNoInterp", Label="ABQ_EChemPET_Cathode_NMC60_Particle1_Layer1_OCPTabularDisCharge" ***** , , ***** [V] [-] (normalization) [K] - Ecker JES 2015a Fig 5(a) 4.582938389, 0 4.545023697, 0.040268456 4.526066351, 0.087248322 4.469194313, 0.134228188 4.393364929, 0.182885906 4.298578199, 0.228187919 4.213270142, 0.275167785 4.146919431, 0.322147651 4.08056872, 0.365771812 4.033175355, 0.411073826 3.985781991, 0.463087248 3.952606635, 0.505033557 3.928909953, 0.55033557 3.91943128, 0.57885906 3.909952607, 0.620805369 3.900473934, 0.67114094 3.881516588, 0.714765101 3.819905213, 0.765100671 3.748815166, 0.812080537 3.706161137, 0.855704698 3.6492891, 0.901006711 3.578199052, 0.947986577 3.511848341, 1 ** SWELLING INFORMATION PER LAYER *Property Table, Type = "ABQ_EChemPET_Electrode_Particle_Layer_SwellingTabular", Label = "ABQ_EChemPET_Cathode_NMC60_Particle1_Layer1_SwellingTabular" 1, 0 1, 1 ** BUTLER VOLMER EQUATIONS *Parameter Table, Type="ABQ_EChemPET_Electrode_Particle_ButlerVolmer", Label="ABQ_EChemPET_Cathode_NMC60_Particle1_ButlerVolmer" ** k_c, k_a,alpha_c,alpha_a, 1.0, 0.0, 0.0, 0.0 ** [-] [-] [-] [-] [mol/m3] [Omega/m2] [-] 2.497e-11, 2.497e-11, 0.473, 0.527, 1.0, 0., 0., 0.0 ** ** ** *Parameter Table, Type="ABQ_EChemPET_Arrhenius", Label="ABQ_EChemPET_Cathode_NMC60_Particle1_BVArrhenius" 43600., 296.15, *Parameter Table, Type="ABQ_EChemPET_Electrode_Particle_PowerLoss", Label="ABQ_EChemPET_Cathode_NMC60_Particle1_PowerLoss" ** , General Assumption 1., 1. *Property Table, Type ="ABQ_EChemPET_Electrode_Particle_dUdTEntropy_Tabular", Label="ABQ_EChemPET_Cathode_NMC60_Particle1_dUdTEntropy_Tabular" ** , - Mastali 2018 Fig 6 (used LiC data) Need to define the unit of dU/dT ** [V/K] [-] -1.80541E-05, 0.001273153 5.8393E-05, 0.051527977 3.41491E-05, 0.104780497 1.68457E-05, 0.154722819 5.3295E-06, 0.204684432 -3.87579E-06, 0.251320414 -2.11752E-05, 0.304596083 -2.45935E-05, 0.351251355 -3.84265E-05, 0.399538578 -4.53092E-05, 0.452848969 -5.79809E-05, 0.504473397 -5.90901E-05, 0.546136366 -7.17541E-05, 0.604427486 -7.51762E-05, 0.647749413 -8.89996E-05, 0.704370001 -9.589E-05, 0.7510137 -0.000123614, 0.797587954 -0.000139756, 0.85086748 -7.48849E-05, 0.89941705 -0.000169731, 0.95243423 -0.000375694, 1.0000 *** *Parameter Table, Type="ABQ_EChemPET_Electrode_PowerLoss", Label="ABQ_EChemPET_Cathode_NMC60_PowerLoss" ** Terms3, term4, term5 Kumaresan A10 1.0, 1.0, 1.0 *Property Table, Type="ABQ_EChemPET_Electrode_ElecCond_Tabular", Label="ABQ_EChemPET_Cathode_NMC60_ElecCond_Tabular", Temperature ** , , -Ecker 2015b Table II 0.681e2, 0.0, 290.15 0.681e2, 1.0, 290.15 0.681e2, 0.0, 298.15 0.681e2, 1.0, 298.15 *Porous Electrode Theory