**----------------------------------------------- ** ANODE **----------------------------------------------- **----------------------------------------------- *material, name=ABQ_EChemPET_matAnode *density 5031.67 *Elastic 1e9, 0.3 *conductivity 1.e-4 *specific heat 1437. *include, input= ecker-electrolyte_propParam-charge.inp *Parameter Table, Type="ABQ_EChemPET_Electrode_Definition", Label="ABQ_EChemPET_Electrode_Definition" "Anode_LiC6", "Anode", 0.671, 0.329, 0.0, 0.445, 1.0, 0.068, 0.637, 0.637, 0.637, 1.0 *Parameter Table, Type="ABQ_EChemPET_Electrode_Particles", Label = "ABQ_EChemPET_Anode_LiC6_Particles" "Particle1", 1.36995e-05, 1.0, 670., "Formulation_Concentration" *Parameter Table, Type="ABQ_EChemPET_Electrode_Particle_Layers", Label="ABQ_EChemPET_Anode_LiC6_Particle1_Layers" "Layer1", 1.0 *Parameter Table, Type="ABQ_EChemPET_Electrode_Particle_Layer_Diffusion", Label="ABQ_EChemPET_Anode_LiC6_Particle1_Layer1_Diffusion" 31920.0 , "DiffusionModel_CoeffSpline", "DiffusionModel_ChemoMech" *Parameter Table, Type="ABQ_EChemPET_Electrode_Particle_Layer_Discretization",Label="ABQ_EChemPET_Anode_LiC6_Particle1_Layer1_Discretization" 100, "Uniform" *** ** *Parameter Table, Type = "ABQ_EChemPET_CubicSplineC2", Label = "ABQ_EChemPET_Anode_LiC6_Particle1_Layer1_DsCubicSpline" *** xStart Xend Coeff_x3, Coeff_x2, Coeff_x1, Coeff_x0 *** yTest = c0*(xTest-xTestMin)**3+ c1*(xTest-xTestMin)**2 + c2*(xTest-xTestMin) + c3 *** where xTestMin = XStart *** ** voa - data generated from Excel file, generated consistently on July 9th ** ** ** smooth data (only 4 points used) ** 0.0 , 0.08367983366666666 , 1.2870245957487487e-11 , 7.873052612699421e-13 , -4.731088419563517e-12 , 1e-12 0.08367983366666666 , 0.16735966733333332 , 1.2870245957487949e-11 , 4.0182453841848386e-12 , -4.328960740875116e-12 , 6.171576201091375e-13 0.16735966733333332 , 0.251039501 , 2.957706730046241e-11 , 7.249185507099845e-12 , -3.38610399804175e-12 , 2.9058927655687464e-13 0.251039501 , 0.33471933466666665 , -5.01693904981073e-11 , 1.4674197723251332e-11 , -1.5515589359153729e-12 , 7.533249152111647e-14 0.33471933466666665 , 0.4183991683333333 , -1.0051267873762059e-11 , 2.0796989671323337e-12 , -1.4959564759555075e-13 , 1.8854765567562447e-14 0.4183991683333333 , 0.502079002 , 2.6918744983615633e-12 , -4.435663043142244e-13 , -1.268433851433095e-14 , 1.500976730421931e-14 0.502079002 , 0.5857588356666666 , -7.162301196841954e-13 , 2.3220052650908804e-13 , -3.0371391643890393e-14 , 1.2419663815148265e-14 0.5857588356666666 , 0.6694386693333333 , -3.2811672797398284e-13 , 5.239847466239736e-14 , -6.556194564161031e-15 , 1.1084455100349321e-14 0.6694386693333333 , 0.7531185029999999 , 1.3692355536634583e-13 , -2.997178499794402e-14 , -4.6795329033456246e-15 , 1.0710483609002669e-14 0.7531185029999999 , 0.8367983366666666 , 8.088020655696331e-14 , 4.4014360163693425e-15 , -6.8192554529224144e-15 , 1.0189259909480995e-14 0.8367983366666666 , 0.9204781703333332 , 9.489104375931035e-14 , 2.4705562711206353e-14 , -4.383586640863005e-15 , 9.696837947641095e-15 0.9204781703333332 , 1.004158004 , 9.489104375931042e-14 , 4.85269629859128e-14 , 1.744498928461815e-15 , 9.558617914231313e-15 ** *Parameter Table, Type="ABQ_EChemPET_Arrhenius", Label="ABQ_EChemPET_Anode_LiC6_Particle1_Layer1_DiffArrhenius" 30300, 296.15, ***-------------------------------------------- *Property Table, Type="ABQ_EChemPET_Electrode_Particle_Layer_OCPTabular", Label="ABQ_EChemPET_Anode_LiC6_Particle1_Layer1_OCPTabular" **** , , **** [V] [-] (normalization) [K] - Ecker JES 2015a Fig 5(a) 1.438220634, 0.00329213 0.854711669, 0.007680356 0.525254409, 0.025798611 0.360563277, 0.04578215 0.27138731, 0.0658503 0.219980463, 0.089322113 0.209832932, 0.133008223 0.192814618, 0.175005961 0.168942826, 0.220357365 0.155362788, 0.264039629 0.148630458, 0.302687548 0.128191174, 0.348042798 0.124897121, 0.388375241 0.125058651, 0.435434246 0.125208643, 0.479131893 0.122001123, 0.544674518 0.101654142, 0.616920627 0.088177944, 0.690855108 0.085356942, 0.869003208 0.085576161, 0.932868999 0.072076888, 1 ** *Parameter Table, Type="ABQ_EChemPET_Electrode_Particle_Layer_OCPTabularNoInterp", Label="ABQ_EChemPET_Anode_LiC6_Particle1_Layer1_OCPTabularCharge" ** , , ** [V] [-] (normalized conc) 1.438220634, 0.00329213 0.854711669, 0.007680356 0.525254409, 0.025798611 0.360563277, 0.04578215 0.27138731, 0.0658503 0.219980463, 0.089322113 0.209832932, 0.133008223 0.192814618, 0.175005961 0.168942826, 0.220357365 0.155362788, 0.264039629 0.148630458, 0.302687548 0.128191174, 0.348042798 0.124897121, 0.388375241 0.125058651, 0.435434246 0.125208643, 0.479131893 0.122001123, 0.544674518 0.101654142, 0.616920627 0.088177944, 0.690855108 0.085356942, 0.869003208 0.085576161, 0.932868999 0.072076888, 1 *Parameter Table, Type="ABQ_EChemPET_Electrode_Particle_Layer_OCPTabularNoInterp", Label="ABQ_EChemPET_Anode_LiC6_Particle1_Layer1_OCPTabularDisCharge" ** , , ** [V] [-] (normalized conc) 1.438220634, 0.00329213 0.854711669, 0.007680356 0.525254409, 0.025798611 0.360563277, 0.04578215 0.27138731, 0.0658503 0.219980463, 0.089322113 0.209832932, 0.133008223 0.192814618, 0.175005961 0.168942826, 0.220357365 0.155362788, 0.264039629 0.148630458, 0.302687548 0.128191174, 0.348042798 0.124897121, 0.388375241 0.125058651, 0.435434246 0.125208643, 0.479131893 0.122001123, 0.544674518 0.101654142, 0.616920627 0.088177944, 0.690855108 0.085356942, 0.869003208 0.085576161, 0.932868999 0.072076888, 1 ** ** ------------------------------------------------------------------ Swelling ** SWELLING INFORMATION PER LAYER *Property Table, Type = "ABQ_EChemPET_Electrode_Particle_Layer_SwellingTabular", Label = "ABQ_EChemPET_Anode_LiC6_Particle1_Layer1_SwellingTabular" 1, 0 1.05, 1 ** SWELLING DIRECTIONAL PROPERTY ***Parameter table, type="ABQ_EChemPET_Electrode_Swelling", Label = "EChemPET_Anode_LiC6_Swelling" **1.,0.,0. ** ------------------------------------------------------------------ Swelling ** ** BUTLER VOLMER EQUATIONS *Parameter Table, Type="ABQ_EChemPET_Electrode_Particle_ButlerVolmer", Label="ABQ_EChemPET_Anode_LiC6_Particle1_ButlerVolmer" ** k_c, k_a, alpha_c, alpha_a, 1.0, 0.0, 0.0, 0.0 ** [-] [-] [-] [-] [mol/m3] [Omega/m2] [-] 1.1942e-10, 1.1942e-10, 0.511, 0.489, 1.0, 0., 0., 0.0 ** ** *Parameter Table, Type="ABQ_EChemPET_Arrhenius", Label="ABQ_EChemPET_Anode_LiC6_Particle1_BVArrhenius" 53400., 296.15, *Parameter Table, Type="ABQ_EChemPET_Electrode_Particle_PowerLoss", Label="ABQ_EChemPET_Anode_LiC6_Particle1_PowerLoss" ** , General Assumption 1., 1. *Property Table, Type ="ABQ_EChemPET_Electrode_Particle_dUdTEntropy_Tabular", Label="ABQ_EChemPET_Anode_LiC6_Particle1_dUdTEntropy_Tabular" ** , - Mastali 2018 Fig 6 (used LiC data) Need to define the unit of dU/dT ** [V/K] [-] 0.000642593, 0 5.92593E-05, 0.100671141 3.14815E-05, 0.110738255 -3.33333E-05, 0.19966443 -0.000107407, 0.30033557 -0.000135185, 0.399328859 -0.000153704, 0.453020134 -0.000156019, 0.473154362 -0.0001375, 0.488255034 -0.000144444, 0.510067114 -5.55556E-06, 0.52852349 -2.87037E-05, 0.55033557 -3.56481E-05, 0.573825503 -3.33333E-05, 0.600671141 -3.56481E-05, 0.654362416 -4.72222E-05, 0.701342282 -4.72222E-05, 0.75 -6.34259E-05, 0.802013423 -7.5E-05, 0.902684564 -0.000100463, 0.94966443 -0.000183796, 1 *** *Parameter Table, Type="ABQ_EChemPET_Electrode_PowerLoss", Label="ABQ_EChemPET_Anode_LiC6_PowerLoss" ** Terms3, term4, term5 Kumaresan A10 1.0, 1.0, 1.0 *Property Table, Type="ABQ_EChemPET_Electrode_ElecCond_Tabular", Label="ABQ_EChemPET_Anode_LiC6_ElecCond_Tabular", Temperature ** , , -Ecker 2015b Table II 0.14e2, 0.0, 290.15, 0.14e2, 1.0, 290.15, 0.14e2, 0.0, 298.15, 0.14e2, 1.0, 298.15, *Porous Electrode Theory